Prabodh Satyal* and Robert S. Pappas
Essential Oil University, New Albanay, IN 47150, USA
*Corresponding author. Email: prabodh@essentialoils.org
FULL TEXT: NVEO 2016, Volume 3, Issue 2, Pages 20-25
Abstract
Properly stored lavender from 1945 was collected in French market and Gas Chromatography and Mass Spectrometry (GCMS) analysis was carried out to see possible chemical transformation and chemical composition. Total of 102 peaks (100% components) were identified, out of them 10 were oxidized minor components (total 0.41%). The lavender essential oil was dominated by the linalool (40.8%), terpinen-4-ol (9.9%), α-terpineol (3.5%), linalyl acetate (16.4%), lavandulyl acetate (3.8%), and trans-caryophyllene (2.2%). Enantiomeric distribution of major monoterpenoids were also measured.
Keywords
Lavender oil-1945, linalool, linalyl acetate, terpinen-4-ol, oxidation, enantiomeric distribution, storage of essential oils.
References
Adams, R. P. (2007). Identification of Essential Oil Components by Gas Chromatography. Illinois: Allured.
Baser, K. H., Özek, T. & Konakchiev, A. (2005). Enantiomeric Distribution of Linalool, Linalyl Acetate and Camphor in Bulgarian Lavender Oil. Journal of Essential Oil Research, 17(2), 135-136.
Chemat, F., Lucchesi, M., Smadja, J., Favretto, L., Colnaghi, G. & Visinoni, F. (2006). Microwave accelerated steam distillation of essential oil from lavender: A rapid, clean and environmentally friendly approach. Analytica Chimica Acta, 555(1), 157-160.
Guenther, E. (1948). The essential oils Vol. I: History origin in plants production analysis. Newyork: Van Nostrand.
Hagvall, L., Sköld, M., Bråred-Christensson, J., Börje, A. & Karlberg, A. (2008). Lavender oil lacks natural protection against autoxidation, forming strong contact allergens on air exposure. Contact Dermatitis, 59(3), 143-150.
Hădărugă, D. I., Hădărugă, N. G., Costescu, C. I., David, I. & Gruia, A. T. (2014). Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system. Beilstein Journal of Organic Chemistry Beilstein J. Org. Chem., 10, 2809-2820.
International Standard ISO 3515 (2002), Oil of lavender (Lavendula angustifolia Mill.)
Lawrence, B. M. (2012). Essential Oils 2008-2011. Carol Stream, IL: Allured.
Letizia, C., Cocchiara, J., Lalko, J. & Api, A. (2003). Fragrance material review on linalyl acetate. Food and Chemical Toxicology, 41(7), 965-976.
Letizia, C., Cocchiara, J., Lalko, J. & Api, A. (2003). Fragrance material review on linalool. Food and Chemical Toxicology, 41(7), 943-964.
Misharina, T., Polshkov, A. N., Ruchkina, E. L. & Medvedeva, I. B. (2003). Changes in the composition of the essential oil of Marjoram during storage. Applied Biochemistry and Microbiology, 39(3), 311-316.
Nilsson, J., Carlberg, J., Abrahamsson, P., Hulthe, G., Persson, B. & Karlberg, A. (2008). Evaluation of ionization techniques for mass spectrometric detection of contact allergenic hydroperoxides formed by autoxidation of fragrance terpenes. Rapid Communications in Mass Spectrometry Rapid Commun. Mass Spectrom., 22(22), 3593-3598.
Pavela, R. (2006). Insecticidal Activity of Essential Oils Against Cabbage Aphid Brevicoryne brassicae. Journal of Essential Oil Bearing Plants, 9(2), 99-106.
Satyal, P. & Pappas, R. S. (2016). First Reporting on the Chemistry and Biological Activity of a Novel Boswellia Chemotype: The Methoxy Alkane Frankincense. Global Journal of Frontier Science Research B, 16, 1-9.
Sköld, M., Borje, A., Matura, M. & Karlberg, A. (2002). Studies on the autoxidation and sensitizing capacity of the fragrance chemical linalool, identifying a linalool hydroperoxide. Contact Dermatitis, 46(5), 267-272.
Sköld, M., Börje, A., Harambasic, E. & Karlberg, A. (2004). Contact Allergens Formed on Air Exposure of Linalool. Identification and Quantification of Primary and Secondary Oxidation Products and the Effect on Skin Sensitization. Chemical Research in Toxicology, 17(12), 1697-1705.
Sköld, M., Karlberg, A., Matura, M. & Börje, A. (2006). The fragrance chemical β-caryophyllene—air oxidation and skin sensitization. Food and Chemical Toxicology, 44(4), 538-545.
Sköld, M., Hagvall, L. & Karlberg, A. (2007). Autoxidation of linalyl acetate, the main component of lavender oil, creates potent contact allergens. Contact Dermatitis, 58(1), 9-4.
Tranchida, P. Q., Shellie, R. A., Purcaro, G., Conte, L. S., Dugo, P., Dugo, G. & Mondello, L. (2010). Analysis of Fresh and Aged Tea Tree Essential Oils by Using GCxGC-qMS. Journal of Chromatographic Science, 48(4), 262-266.
Turek, C. & Stintzing, F. C. (2013). Stability of essential oils: a review. Comprehensive Reviews in Food Science and Food Safety, 12(1), 40-53.
Cite
| Bibtex | @ { nveo260180, journal = {Natural Volatiles \& Essential Oils}, issn = {}, eissn = {2148-9637}, address = {Badebio Biotechnology Ltd.}, year = {2016}, volume = {3}, pages = {20 – 25}, doi = {}, title = {Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution}, key = {cite}, author = {Satyal, Prabodh and Pappas, Robert S.} } |
| APA | Satyal, P , Pappas, R . (2016). Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution. Natural Volatiles & Essential Oils, 3 (2), 20-25. Retrieved from http://dergipark.gov.tr/nveo/issue/24570/260180 |
| MLA | Satyal, P , Pappas, R . “Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution”. Natural Volatiles & Essential Oils 3 (2016): 20-25 <http://dergipark.gov.tr/nveo/issue/24570/260180> |
| Chicago | Satyal, P , Pappas, R . “Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution”. Natural Volatiles & Essential Oils 3 (2016): 20-25 |
| RIS | TY – JOUR T1 – Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution AU – Prabodh Satyal , Robert S. Pappas Y1 – 2016 PY – 2016 N1 – DO – T2 – Natural Volatiles & Essential Oils JF – Journal JO – JOR SP – 20 EP – 25 VL – 3 IS – 2 SN – -2148-9637 M3 – UR – Y2 – 2019 ER – |
| EndNote | %0 Natural Volatiles & Essential Oils Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution %A Prabodh Satyal , Robert S. Pappas %T Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution %D 2016 %J Natural Volatiles & Essential Oils %P -2148-9637 %V 3 %N 2 %R %U |
| ISNAD | Satyal, Prabodh , Pappas, Robert S. . “Antique Lavender Essential Oil from 1945, its chemical composition and enantiomeric distribution”. Natural Volatiles & Essential Oils 3 / 2 (August 2016): 20-25. |
FULL TEXT: NVEO 2016, Volume 3, Issue 2, Pages 20-25
